Exporting and saving Google Chrome Bookmarks are one and the same, as the export function will create an HTML file that can be imported into a different browser to create and save your bookmarks.

Executable file types such as .exe. .bat or .msi are not supported to automatically open after download in Google Chrome as once opened, these files can automatically execute themselves.

If you want links in Outlook to be opened in Chrome, this post will show you how to set Chrome as a default browser for Outlook links.